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Lactones. Part 16: Lactonization of γ,δ-epoxy esters with p-toluenesulfonic acid monohydrate

✍ Scribed by Czesław Wawrzeńczyk; Małgorzata Grabarczyk; Agata Białońska; Zbigniew Ciunik


Book ID
104205622
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
229 KB
Volume
59
Category
Article
ISSN
0040-4020

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✦ Synopsis


The reaction of cyclic g,d-epoxy esters with p-toluenesulfonic acid monohydrate is described. The reaction carried out in benzene or methylene chloride gave tosyloxy lactones as product. The ethoxy or methoxy lactones were obtained when ethanol or methanol were used as solvent. A mechanism of this lactonization is proposed.


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ChemInform Abstract: Lactones. Part 5. S
✍ T. Olejniczak; J. Nawrot; Z. Ciunik; C. Wawrzenczyk 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

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