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Laboratory studies of the OH-initiated photooxidation of Di-n-propyl ether

โœ Scribed by John Sempeles; Jean M. Andino


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
264 KB
Volume
32
Category
Article
ISSN
0538-8066

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## Abstract Oxygenated compounds such as ethers and alcohols are used as gasoline additives and industrial solvents. However, despite their widespread use, the atmospheric reaction mechanisms of some of these compounds are unknown. This study examines the ^ยท^OHโ€initiated gasโ€phase removal mechanism

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Using relative rate methods, rate constants for the gas-phase reactions of OH radicals and Cl atoms with di-n-propyl ether, di-n-propyl ether-d 14 , di-n-butyl ether and di-nbutyl ether-d 18 have been measured at 296 ฯฎ 2 K and atmospheric pressure of air. The rate constants obtained (in cm 3 molecul