## Abstract A fast and simple screening procedure using solidβphase microextraction and gas chromatographyβmass spectrometry (SPMEβGCβMS) in fullβscan mode for the determination of volatile organic compounds (VOC) is presented. The development of a fast and simple screening technique for the simult
Laboratory and field screening strategies for measuring volatile organic compounds in landfill gas
β Scribed by C.W. Emerson
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 107 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0301-4797
No coin nor oath required. For personal study only.
β¦ Synopsis
These patterns can be used to select efficient screening tools, or groups of compounds that provide the most information on overall occurrences of a larger target group of compounds. By using these screens to indicate whether a sample is contaminated with detectable amounts of the compounds of interest, attention can be focused on those samples considered most likely to contain measurable concentrations of targeted compounds. The cost savings that result from eliminating samples that are most likely uncontaminated can be applied to obtaining additional samples that more accurately characterize the spatial or temporal variability of the environmental problem. In a retrospective application of screening techniques to the State of California's database of volatile organic compounds in landfill gas, two laboratory screening compounds, perchloroethylene and methylene chloride, represent over 95% of the total number of positive detections of a target group of 10 volatile organic compounds. Benzene and vinyl chloride, two field screening compounds that were selected using the characteristics of commercially available colorimetric detector tubes, recorded 74% of the total contaminant detections and a 52% saving in analytical costs as compared to an exhaustive analysis of every sample for all 10 volatile organic compounds. The number of detections recorded could have been improved if more sensitive and less selective field screening devices were available.
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A sensitive screening method with low sample consumption is presented for the simultaneous determination of 48 volatile organic compounds (VOCs) by capillary gas chromatography with flame ionization detection (FID) or mass spectrometric ion trap detection (ITD). The method is applicable to body flui