Labelling of Organic Compounds by Mercury-photosensitized Reaction with Tritium Gas
β Scribed by CACACE, FULVIO; GUARINO, ANGELO; MONTEFINALE, GABRIELLA
- Book ID
- 109613469
- Publisher
- Nature Publishing Group
- Year
- 1961
- Tongue
- English
- Weight
- 215 KB
- Volume
- 189
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/189054a0
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## Abstract A range of organic substrates was successfully exchanged with tritium gas using NaBH~4~βreduced palladium oxide or chloride as catalyst. Exchange conditions involved a reaction temperature of 100 Β°C, a reaction time of 3 days, and products were analyzed by radioβgas chromatography and ^
## Abstract In a new approach to the specific labelling of organic compounds with tritium use is made of isotope exchange with tritium of certain specific hydrogen atoms in organic molecules when stirred with tritium gas in solution at room temperature in the presence of a metal hydrogen transfer c