𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Labelled compounds of potential biological interest VII. Synthesis of 3-deoxy-D-manno-[1-14C]octulosonic acid (D-manno-KDO) of high specific activity

✍ Scribed by Göran Bondesson; Ingrid Fagervall; Tamas Gosztonyi; Anita Jansson; Annesophie Ohlberger; Astra Läkemedel Ab


Publisher
John Wiley and Sons
Year
1982
Tongue
French
Weight
290 KB
Volume
19
Category
Article
ISSN
0022-2135

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

The preparation of the title compound from 2‐deoxy‐D‐manno‐heptose with potassium [^14^C] cyanide followed by subsequent oxidation is reported. Frequent use of HPLC has made it possible to follow and optimize the different reaction steps. The synthesis was carried out on the millimole level and the product had a specific activity of 50 mCi/mmol.