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L-chiro-Inositol Derivatives from myo-Inositol. Building Blocks for Inositolphosphoglycans.

✍ Scribed by M. Belen Cid; Francisco Alfonso; Manuel Martin-Lomas

Publisher
John Wiley and Sons
Year
2003
Weight
111 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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t\_-Quebrachitol was O-demethylated to give lt\_-chiro-inositol which, on treatment with dibutyltin oxide, benzyl chloride, and tetrabutylammonium iodide in acetonitrile, gave mainly crystalline lo-2,3,5tri-0-benzyl-chiro-inositol (Sal together with lt\_-2,3,5,6-tetra-0-benzyl-chiro-inositol. Catal