✦ LIBER ✦
Kristallstruktur von [ZnH(NPMe3)]4, einem tetrameren Phosphaniminato-Komplex des Zinks mit terminalen Hydrido-Liganden
✍ Scribed by Matthias Krieger; Bernhard Neumüller; Kurt Dehnicke
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- German
- Weight
- 51 KB
- Volume
- 624
- Category
- Article
- ISSN
- 0372-7874
No coin nor oath required. For personal study only.
✦ Synopsis
The crystal structure of the title compound, which crystallizes as [ZnH(NPMe 3 )] 4 ´4 THF forming colourless, very reactive blocks, obtained by recrystallization from toluene, reveals discrete tetrameric molecules with heterocubane structure with almost undistorted Zn 4 N 4 cubic skeletons. The hydrido ligands assume terminal exocyclic positions with Zn±H bond lengths of 150 pm in average.