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Kreuzkonjugierte Cyanine und Merocyanine aus Salzen des 1-substituierten 2,3-Dimethylchinoxalins (Vinyloge von Indigo-imiden mit cyclisch eingebauter Imidfunktion). Vorläufige Mitteilung

✍ Scribed by Dieter Schelz


Publisher
John Wiley and Sons
Year
1977
Tongue
German
Weight
184 KB
Volume
60
Category
Article
ISSN
0018-019X

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✦ Synopsis


Crossed conjugated Cyanines and Merocyanines, obtained from Salts of 1‐substituted 2,3‐Dimethyl‐quinoxalines. (A second type of vinylogous Indigo‐imides.) Preliminary Communication.

On dissolving quaternary salts of 2,3‐dimethylquinoxaline in dimethylformamide or dimethylsulfoxide, a spontaneous reaction takes place: the title compounds are isolated from the reaction mixtures; they are easily oxidized, e.g. by MnO~2~. Mechanistic aspects are discussed.