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Konsequenzen einer Einschränkung des Porphyrin-π-Systems: Versuche zur Synthese des Bakteriophins und Chlorophins

✍ Scribed by Bohusch, Michael ;Flitsch, Wilhelm ;Kneip, Heinz-Gerd


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
407 KB
Volume
1991
Category
Article
ISSN
0947-3440

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✦ Synopsis


Consequences of a Diminution of the Porphyrin π‐System: Attempted Syntheses of Bacteriophin and Chlorophin

A report is given on a synthesis of bacteriophin (1) from 2,5‐disubstituted pyrrole derivatives. Spectroscopic properties of 1 resemble those of octaethylbacteriochlorin. Starting from 2,2‐dipyrrylmethane and 2‐(2‐aminoethyl)pyrrole the chlorophin derivative 6 has been obtained.