✦ LIBER ✦
Komplexchemie reaktiver organischer Verbindungen, XXI: Über eine einfache Synthese der Rhenium-Halbsandwich-Komplexe (η-C5H4)Re(CO)3 [X Cl, Br, I]
✍ Scribed by Herrmann, Wolfgang A.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1978
- Tongue
- English
- Weight
- 202 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0009-2940
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✦ Synopsis
Complex Chemistry of Reactive Organic Compounds, XXI: On a Simple Synthesis of the Halfsandwich Rhenium Complexes (η‐C~5~H~4~X)Re(CO)~3~ [X = Cl, Br, I]
Tricarbonyl(η‐chlorocyclopentadienyl)rhenium (3a), (η‐bromocyclopentadienyl)tricarbonylrhenium (3b), and tricarbonyl(η‐iodocyclopentadienyl)rhenium (3c) are formed in one‐step, high‐yield syntheses by cyclopentadienylation of the corresponding pentacarbonylrhenium halides (CO)~5~ReX [X Cl (1a), Br (1b), I (1c)] with diazocyclopentadiene (2).