✦ LIBER ✦
Kinetische Studie zur Aminolyse von «aktiven Estern» bei der Peptidsynthese. 3. Mitteilung über chemische Struktur und UV.-Spektroskopie
✍ Scribed by K. Stich; H. G. Leemann
- Publisher
- John Wiley and Sons
- Year
- 1963
- Tongue
- German
- Weight
- 494 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
By means of spectrophotometric measurements the order of reaction in the aminolysis of «active esters» has been determined. In order to compare the reaction velocities of various «active esters», test conditions have been chosen so that «pseudo‐first order» reactions occur; this allows the characterization of the different «active esters» based on a half‐value period which is independent of concentration.