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Kinetics theory of anionic copolymerization with constant monomer ratio, 1. Sequence distribution

✍ Scribed by Hu, Xiaodong ;Yan, Deyue

Publisher: Wiley (John Wiley & Sons)
Year: 1992
Weight: 319 KB
Volume: 1
Category: Article
ISSN: 1018-5054
DOI: 10.1002/mats.1992.040010305

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✦ Synopsis

Abstract

The chain microstructure of copolymers generated via anionic copolymerization with constant monomer ratio is studied theoretically by using the linear operator technique to solve the kinetic differential equations. The microstructural parameters for copolymers, such as the functions of sequence distributions, average length of the sequence and fractions of dyads and triads, are derived and further connected with initial conditions and reaction time so that one can predict the chain microstructure for copolymers from the polymerization conditions.

📜 SIMILAR VOLUMES

Kinetic theory of anionic copolymerizati

Kinetic theory of anionic copolymerization with constant monomer ratio, 2 . Molecular weight distribution

✍ Hu, Xiaodong ;Yan, Deyue ;Feng, Jing 📂 Article 📅 1992 🏛 Wiley (John Wiley & Sons) ⚖ 372 KB

## Abstract The kinetic differential equations for the anionic copolymerization with constant monomer ratio are treated by Laplace transformation and a graphical technique. A theoretical method is established by which all molecular parameters of the copolymers, such as the molecular distribution (M