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Kinetics Study and Theoretical Modeling of the Diels−Alder Reactions of Cyclopentadiene and Cyclohexadiene with Methyl Vinyl Ketone. The Effects of a Novel Organotungsten Catalyst

✍ Scribed by Fu, Yaw-Shien; Tsai, Shih-Chung; Huang, Chun-Huei; Yen, Shih-Yao; Hu, Wei-Ping; Yu, Shuchun Joyce


Book ID
126979341
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
220 KB
Volume
68
Category
Article
ISSN
0022-3263

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Intermolecular Hetero Diels-Alder Reacti
✍ Buback, Michael ;Kuchta, Gabriele ;Niklaus, Anja ;Henrich, Marielouise ;Rothert, 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 867 KB

## Abstract The hetero Diels‐Alder reactions of enamino ketones 1 and 2 with the vinyl ethers 3–5a are studied in dichloromethane solution under high pressures up to 5 kbar. The kinetics is measured by on‐line FT‐IR spectroscopy to 3 kbar. The cycloaddition reactions of enamino ketones 1 and 2 with