## Abstract Free radical copolymerization of an acyclic monoterpenoid linalool (LIN) and methyl methacrylate (MMA) in dioxan was carried out in dilatometer under an inert atmosphere of nitrogen for 90 min at 60 ± 1°C by using diphenyl selenonium 2,3,4,5‐tetraphenylcyclopentadienylide (selenonium yl
Kinetics of ylide-initiated radical copolymerization of 4-vinylpyridine and methyl methacrylate
✍ Scribed by Vasishtha, Rita ;Awasthi, Sanjay ;Srivastava, A. K.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1990
- Tongue
- English
- Weight
- 319 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0007-1641
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📜 SIMILAR VOLUMES
## Abstract The free‐radical copolymerization of 4‐vinyl pyridine (4‐VP) with methyl acrylate (MA) initiated by __p__‐acetylbenzylidene triphenylarsonium ylide at 60 ± 0.1°C with dioxane as an inert solvent yielded random copolymers. The kinetic equation was __R__~__p__~ ∝ [Ylide]^0.83^[4‐VP]^0.33^
## Abstract Copolymerizations of methyl methacrylate (MMA) with 4‐vinylpyridine (4VP) were performed from different monomer feed ratios in 1,4‐dioxan at 30°C under free radical initiation experimental conditions, using Ni(II)α‐Benzoinoxime complex as initiator. The obtained copolymers (PMMA4VP) wer