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Kinetics of Thermal Rearrangements in the Δ 2 -Thujene System: A Full Quadrisection of a Perturbed Bicyclo[3.1.0]hex-2-ene

✍ Scribed by Doering, William von E.; Zhang, Ting-hu; Schmidt, Eckhart K. G.


Book ID
127261667
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
192 KB
Volume
71
Category
Article
ISSN
0022-3263

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AS an extension of our studies on the photochemical Diels-Alder reaction of 1,3,5-hexatrienes to bicyclo[3.l.O]hex-2-enes, 1 we became interested in determining the stereochemical consequences attending the thermal cycloreversion of the bicyclo[3.l.O]hex-2-ene system. The parent carbocycle is known