## Abstract Rate constants for the unimolecular thermal isomerization of gaseous 1,1‐dimethylcyclopropane to isomeric methylbutenes have been measured, and Arrhenius parameters determined, over a wide temperature range, 683–1132 K, using a single‐pulse shock tube and a static reactor. For the overa
Kinetics of thermal isomerization of 1-methyldicyclopentadiene
✍ Scribed by V. A. Mironov; T. M. Fadeeva; A. A. Akhrem
- Book ID
- 112434139
- Publisher
- Springer
- Year
- 1968
- Tongue
- English
- Weight
- 214 KB
- Volume
- 17
- Category
- Article
- ISSN
- 1573-9171
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## Abstract The Arrhenius parameters for the gas phase, unimolecular structural isomerizations of 1,1,2‐trimethylcyclopropane to three isomeric methylpentenes and two dimethylbutenes have been determined over a wide range of temperatures, 688–1124 K, using both static and shock tube reactors. For t
## Abstract Reaction rates for the structural isomerization of 1,1,2,2‐tetramethylcyclopropane to 2,4‐dimethyl‐2‐pentene have been measured over a wide temperature range, 672–750 K in a static reactor and 1000–1120 K in a single‐pulse shock tube. The combined data from the two temperature regions g