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Kinetics of the Volume and Surface Reactions in the Phase-Transfer Catalytic Aminolysis of 4-Nitrophenyl Acetate

โœ Scribed by L. N. Vakhitova; A. F. Popov; Ya. F. Burdina; V. A. Savelova; I. A. Belousova


Book ID
111613161
Publisher
Springer
Year
2004
Tongue
English
Weight
84 KB
Volume
40
Category
Article
ISSN
0040-5760

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๐Ÿ“œ SIMILAR VOLUMES


Kinetics and mechanism of the aminolysis
โœ Enrique A. Castro; Leonardo Leandro; Josรฉ G. Santos ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 93 KB ๐Ÿ‘ 2 views

The reactions of the title substrate (1) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanol-water, at 25.0ะŠC, ionic strength 0.2 M (KCl). Under amine excess over the substrate, pseudo-first-order rate coefficients (k obs ) are obtained. Plots of k

Kinetics and mechanism of the aminolysis
โœ Enrique A. Castro; Monica Andujar; Paola Campodonico; Josรฉ G. Santos ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 134 KB

## Abstract The reactions of 4โ€methylphenyl 4โ€nitrophenyl carbonate (MPNPC) and 4โ€methylphenyl 2,4โ€dinitrophenyl carbonate (MPDNPC) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanolโ€“water, at 25.0ยฐC, ionic strength 0.2 M (KCl). Under amine excess