Kinetics of the Volume and Surface Reactions in the Phase-Transfer Catalytic Aminolysis of 4-Nitrophenyl Acetate
โ Scribed by L. N. Vakhitova; A. F. Popov; Ya. F. Burdina; V. A. Savelova; I. A. Belousova
- Book ID
- 111613161
- Publisher
- Springer
- Year
- 2004
- Tongue
- English
- Weight
- 84 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-5760
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๐ SIMILAR VOLUMES
The reactions of the title substrate (1) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanol-water, at 25.0ะC, ionic strength 0.2 M (KCl). Under amine excess over the substrate, pseudo-first-order rate coefficients (k obs ) are obtained. Plots of k
## Abstract The reactions of 4โmethylphenyl 4โnitrophenyl carbonate (MPNPC) and 4โmethylphenyl 2,4โdinitrophenyl carbonate (MPDNPC) with a series of secondary alicyclic amines are subjected to a kinetic investigation in 44 wt% ethanolโwater, at 25.0ยฐC, ionic strength 0.2 M (KCl). Under amine excess