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Kinetics of the uninhibited and ethanol-inhibited CoO, Co2O3and Ni2O3catalyzed autoxidation of sulfur(IV) in alkaline medium

โœ Scribed by K. S. Gupta; R. K. Mehta; A. K. Sharma; P. K. Mudgal; S. P. Bansal


Publisher
Springer
Year
2008
Tongue
English
Weight
416 KB
Volume
33
Category
Article
ISSN
0340-4285

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Kinetics of the simultaneous oxidation o
โœ Anil Kumar Sharma; Punit Kumar Mudgal; S. P. Bansal; K. S. Gupta ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 459 KB ๐Ÿ‘ 2 views

## Abstract In the Ni(II)โ€“S(IV)โ€“O~2~ system in the region of pH > 8.4, both Ni(II) and S(IV) are simultaneously autoxidized, and when sulfur is consumed fully NiOOH precipitates. At pH > 8.4, ethanol has no effect on the rate, whereas ammonia strongly inhibits the reaction when pH > 7.0. The kineti