Kinetics of the Thermal Isomerization of Methylcyclopropane †
✍ Scribed by Kalra, Bansi L.; Cho, Janet Y.; Lewis, David K.
- Book ID
- 126837276
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 31 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
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## Abstract Reaction rates for the structural isomerization of 1,1,2,2‐tetramethylcyclopropane to 2,4‐dimethyl‐2‐pentene have been measured over a wide temperature range, 672–750 K in a static reactor and 1000–1120 K in a single‐pulse shock tube. The combined data from the two temperature regions g
## Abstract The Arrhenius parameters for the gas phase, unimolecular structural isomerizations of 1,1,2‐trimethylcyclopropane to three isomeric methylpentenes and two dimethylbutenes have been determined over a wide range of temperatures, 688–1124 K, using both static and shock tube reactors. For t