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Kinetics of the thermal isomerization of 7,7-dimethylbicyclo[4.1.1]octa-2,4-diene and 8,8-dimethylbicyclo[5.1.0]octa-2,4-diene. Evidence for a nonconcerted 1,5-carbon sigmatropic shift

โœ Scribed by Gajewski, Joseph J.; Gortva, Andrea M.; Borden, Weston Thatcher.


Book ID
127260745
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
300 KB
Volume
108
Category
Article
ISSN
0002-7863

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โœ F.A.L. Anet; Duncan P. Mullis ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 170 KB

Recently Pappas and Pappas (1) have shown that acetylenes add photochemically to methoxy-p-benzoquinone to give derivatives of bicyclo[4.2.0]octa-3,7-diene-2,5-dione, The exact structure (Ia or Ib) of the phenylacetylene-methoxybenzoquinone adduct I was not determined. We have now found that this ad