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Kinetics of the substitution of the cyclooctadiene ligand in β-diketonatocyclooctadienerhodium(I) complexes by triphenylphosphite

✍ Scribed by Johann G. Leipoldt; Gert J. Lamprecht; E.C. Steynberg


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
390 KB
Volume
397
Category
Article
ISSN
0022-328X

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## Abstract The kinetics of the reaction have been studied in toluene solution. The reaction occurs by a dissociative mechanism and the observation of an appreciable mass law retardation effect shows that Fe(CO)~4~ is produced as an intermediate. Analysis of the effect of the substituent X on t

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The complex [Fe(imox) (Nmim)~], where imox is a planar bis(iminooxime) macrocyclic ligand and Nmim = N-methyl imidazole, undergoes substitution reactions in the presence of 2,2'bipyridine (bipy), leading to a series of intermediate mixed complexes. The forward and reverse rate constants for the subs