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Kinetics of the reactions of methylene (X3B1)-radicals with nitric oxide and nitrogen dioxide

โœ Scribed by Seidler, V.; Temps, F.; Wagner, H. G.; Wolf, M.

Book ID
115489596
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
447 KB
Volume
93
Category
Article
ISSN
0022-3654

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The reaction of methoxy radicals with ni
The reaction of methoxy radicals with nitric oxide and nitrogen dioxide
โœ L. Batt; G. N. Rattray ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 550 KB

By allowing dimethyl peroxide ( 10-4M) to decompose in the presence of nitric oxide (4.5 X lOW5M), nitrogen dioxide (6.5 X 10-5M) and carbon tetrafluoride (500 Torr), it has been shown that the ratio kzlkz, = 2.03 f 0.47: CH30 + NO -CH30NO (reaction 2) and CH30 + NO2 -CH30N02 (reaction 2'). Deviatio