Kinetics of the reactions of atomic bromine with HO2 and H2O2
β Scribed by Jessica Posey; John Sherwell; Myron Kaufman
- Book ID
- 107732786
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 341 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
The kinetics and mechanism of the reaction Cl Ο© HO 2 : products (1) have been studied in the temperature range 230-360 K and at total pressure of 1 Torr of helium using the discharge-flow mass spectrometric method. The following Arrhenius expression for the total rate constant was obtained either fr
HO2 profiles in the thermal decomposition of H,02 in shock waves over the range 1000-1250 K were analyzed with respect to the reactions HO+HZOz+HOz+H20 (3) and HO+H0r~Hz0+02 (4). Reaction (3) shows a strong up-turn ofthe rate constant at temperatures near 800 K. Over the range 250-1250 K, k, can be
## Abstract The kinetics of the hydrogen abstraction from H~2~O~2~ by ^β’^OH has been modeled with MP2/6β31G\*//MP2/6β31G\*, MP2βSAC//MP2/6β31G\*, MP2/6β31+G\*\*//MP2/6β31+G\*\*, MP2βSAC// MP2/6β31+G\*\*, MP4(SDTQ)/6β311G\*\*//MP2/6β31G\*, CCSD(T)/6β31G\*//CCSD(T)/6β31G\*, CCSD(T)/6β31G\*\*//CCSD(T)