✦ LIBER ✦

Kinetics of the reaction of pure CO2 with N-methyldiethanolamine in aqueous solutions

✍ Scribed by Fernando Camacho; Sebastián Sánchez; Rafael Pacheco; M. Dolores La Rubia; Antonio Sánchez

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 207 KB
Volume: 41
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.20375

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The process of pure carbon dioxide absorption is analyzed in aqueous solutions of N‐methyldiethanolamine (MDEA). The experiments were made in a stirred tank reactor with a plane and known interface area. The variables considered were the MDEA concentration within the range 0.1–3.0 M and the temperature in the interval 288–313 K. From the results, we deduce that the process takes place under isothermal conditions and moderately fast regime, with second‐order kinetics. We determined a reaction order of one with respect to the amine, and an expression for the kinetic constant valid throughout the entire range of temperatures and concentrations assayed ln k = 22.4 − 6243.5/T. © 2008 Wiley Periodicals, Inc. Int J Chem Kinet 41: 204–214, 2009

📜 SIMILAR VOLUMES

Absorption of CO2 and N2O into aqueous s

Absorption of CO2 and N2O into aqueous solutions of methyldiethanolamine

✍ Raymond A. Tomcej; Fred D. Otto 📂 Article 📅 1989 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 312 KB 👁 2 views

Kinetics of the reaction of carbon dioxi

Kinetics of the reaction of carbon dioxide with aqueous 2-piperidineethanol solutions

✍ Shuo Xu; Yi-Wei Wang; Frederick D. Otto; Alan E. Mather 📂 Article 📅 1993 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 407 KB 👁 2 views

Kinetics of the disproportionation react

Kinetics of the disproportionation reaction of HIO2 in acidic aqueous solutions

✍ Smiljana Marković; Biljana Petrović 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 91 KB 👁 1 views

We review and discuss kinetic studies of the disproportionation reaction of iodous acid (HIO 2 ) in the presence of excess of Hg 2+ -ions. The reactions are followed at different temperatures in water solution with strongly defined acidity. The rate constants of disproportionation are determined bet

A Study on CO2 Absorption Kinetics by Aq

A Study on CO2 Absorption Kinetics by Aqueous Solutions of N,N-Diethylethanolamine and N-Ethylethanolamine

✍ P. D. Vaidya; E. Y. Kenig 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 123 KB 👁 2 views

Kinetics of the reaction of CO2 with aqu

Kinetics of the reaction of CO2 with aqueous potassium salt of taurine and glycine

✍ P. S. Kumar; J. A. Hogendoorn; G. F. Versteeg; P. H. M. Feron 📂 Article 📅 2003 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 183 KB 👁 1 views

Kinetics of CN reactions with N2O and CO

Kinetics of CN reactions with N2O and CO2

✍ N. S. Wang; D. L. Yang; M. C. Lin; C. F. Melius 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 493 KB 👁 1 views

The rate constants for the reaction of CN with NzO and COz have been measured by the laser dissociation/laser-induced fluorescence (two-laser pump-probe) technique at temperatures between 300 and 740 K. The rate of CN + NzO was measurable above 500 K, with a least-squares averaged rate constant, k =