Arylhydrazines were treated with nitric oxide in tetrahydrofuran in the presence of oxygen to afford dehydrazinated compounds in good yields accompanied by small amounts of arylazides. 0 1997 Elsevier Science Ltd. Nitric oxide (NO) is a gaseous radical molecule which has been revealed to play a var
Kinetics of the Reaction of Nitric Oxide with Molecular Oxygen
✍ Scribed by ŠOLC, M.
- Book ID
- 109648083
- Publisher
- Nature Publishing Group
- Year
- 1966
- Tongue
- English
- Weight
- 114 KB
- Volume
- 209
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/209706a0
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📜 SIMILAR VOLUMES
Rate constants for the reactions of 1 -and 2-hydroxyethyl radicals with O2 and NO were measured at room temperature by laser flash photolysis-photoionization mass spectrometry method. The results are as follows (in units of cm3 moleculec' s-I): CH>CHOH+O> ((2.8+0.2)x10-I'); CH,CHOH+NO ((2.4kO.6)XlWI
The shock tube data of Ogura [51 on the pyrolysis of CzHz/NO mixtures (1100-1500 K) is shown to be consistent with a simple mechanism whereby radicals are both initiated and terminated by NO (Scheme I). The scheme accounts for the rate of formation of the main product, vinylacetylene (VA), the lesse