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Kinetics of the reaction of malachite green and crystal violet with formally aprotic solvents

✍ Scribed by Marek K. Kalinowskil; Jarosz.xl;law Stachurskil; Konard R. Janowskil

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 376 KB
Volume: 117
Category: Article
ISSN: 0003-2670
DOI: 10.1016/0003-2670(80)87037-1

No coin nor oath required. For personal study only.

✦ Synopsis

The stability of malachite green and crystal violet has heen studied spectrophotometrically in 17 formally aprotic media. The cations of these compounds react with solvents that are Lewis bases; the pseudo-first order rate constant values (k') are dependent on Cutmann's donor numbers. The sensitivity of the two dyes to the solvent effect correlates with the net charge on their central carbon atoms.

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