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Kinetics of the reaction of iodine with hypophosphorous acid and with hypophosphites

โœ Scribed by Griffith, R. O.; McKeown, A.; Taylor, R. P.


Book ID
120631700
Publisher
Royal Society of Chemistry
Year
1940
Weight
997 KB
Volume
36
Category
Article
ISSN
0014-7672

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The gas-phase reaction CH3SH + IZ has been studied spectrophotometrically over the temperature range of 476-604 K. It was found that the reaction undergoes H abstraction by I at 5575 K, leading to the formation of MeSI and followed by a secondary reaction which leads to the formation of MeSSMe: Tak