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Kinetics of the reaction of a secondary alkyl radical with tri-n-butylgermanium hydride and calibration of a secondary alkyl radical clock reaction

✍ Scribed by Lusztyuk, J.; Maillard, B.; Deycard, S.; Lindsay, D. A.; Ingold, K. U.

Book ID
127177596
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
811 KB
Volume
52
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

The free-radical reaction of tri-n-butyl
The free-radical reaction of tri-n-butyltin hydride with peroxides
✍ J. L. Brokenshire; K. U. Ingold πŸ“‚ Article πŸ“… 1971 πŸ› John Wiley and Sons 🌐 English βš– 744 KB

## Abstract Rate constants for the tri‐__n__‐butyltin radical (**Sn Β·**) induced decomposition of a number of peroxides have been measured in benzene at 10Β°C. The values range from ∼100 __M__^βˆ’1^ sec^βˆ’1^ for di‐__t__‐butyl peroxide to 2.6 Γ— 10^7^ __M__^βˆ’1^ sec^βˆ’1^ for di‐__t__‐butyl diperoxyisophth

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The kinetics and absolute rate constants for the free-radical chain reaction of tri-nbutyltin hydride with di-t-butyl disulfide have been measured in cyclohexane at 30". The rate controlling step for chain propagation involves the cleavage of the disulfide bond by an attacking tributyltin radical. T