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Kinetics of the reaction aluminum(2P0) + water over an extended temperature range

✍ Scribed by McClean, Roy E.; Nelson, H. H.; Campbell, Mark L.

Book ID: 121358160
Publisher: American Chemical Society
Year: 1993
Tongue: English
Weight: 439 KB
Volume: 97
Category: Article
ISSN: 0022-3654
DOI: 10.1021/j100140a024

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Kate constants for the reaction O(3P) + SO2 + M have been determined over the temperature range of 299"-440"K, using a flash photolysis-NO2 chemiluminescence technique. For M=Ar, the Arrhenius expression k2Ar = 3.1 X 10-32e-'2005\*3")'RT cm6/molec2 ~ sec was obtained. A t room temperature kqAr = (1.