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Kinetics of the rapid interaction of chromium(III) with iodate and sulfite

โœ Scribed by Bazsa, Gy. ;Diebler, H.

Book ID
112685286
Publisher
Springer
Year
1975
Tongue
English
Weight
334 KB
Volume
2
Category
Article
ISSN
0133-1736

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The reaction of trans-[Cr(Salen)(OH 2 ) 2 ] ฯฉ with aqueous sulfite yields trans-[Cr(Salen)(OH 2 )(OSO 2 9 O)] ฯช (O-bonded isomer). The rate and activation parameter data for the formation of the sulfito complex are consistent with a mechanism involving rate-limiting addition of SO 2 to the bond. The