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Kinetics of the Oxygenation of Unsaturated Organics with Singlet Oxygen Generated from H 2 O 2 by a Heterogeneous Molybdenum Catalyst

✍ Scribed by Sels, Bert F.; De Vos, Dirk E.; Jacobs, Pierre A.


Book ID
125892848
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
330 KB
Volume
129
Category
Article
ISSN
0002-7863

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Singlet oxygen generation from H2O2/MoO4
✍ VΓ©ronique Nardello; StΓ©phane Bogaert; Paul L Alsters; Jean-Marie Aubry πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 104 KB

Seventeen organic solvents are screened as reaction media to conduct the molybdate-catalyzed disproportionation of hydrogen peroxide into singlet molecular oxygen, 1 O 2 ( 1 D g ). The solvents are investigated by resorting to the detection of the infra-red luminescence of 1 O 2 at 1270 nm. Preparat