The kinetics of the oxidation of formate, oxalate, and malonate by [Ni III (L 1 )] 2Ο© (where HL 1 Ο 15-amino-3-methyl-4,7,10,13-tetraazapentadec-3-en-2-one oxime) were carried out over the regions pH 3.0 -5. 75, 2.80 -5.50, and 2.50 -7.58, respectively, at constant ionic strength and temperature 40Π
Kinetics of the oxidation of iodide by copper(III)-imine-oxime complexes
β Scribed by Najat I. Al-Shatti; Mohamed A. Hussein; Yousif Sulfab
- Publisher
- Springer
- Year
- 1984
- Tongue
- English
- Weight
- 490 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0340-4285
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The iron(II) complex of H 2 L 14-dimethyl-4, 7, 10, 13-tetraazahexadeca-(H L Ο 3, 2 3,13-diene-2,15-dione dioxime, Coord. Chem. Rev., 33, 87 (1980)) is oxidized by periodate very rapidly in the range pH 2.0-7.0, and the kinetics of the reaction has been followed by stoppedflow spectrophotometry at 3
## Abstract The kinetics of the oxidation of iodide by hydrogen peroxide catalyzed by acidic molybdate have been studied by a spectrophotometric stoppedβflow method. The results are interpreted in terms of the mechanism equation image and the implied rate law where [mol] is total analytical conc