Kinetics of the oxidation of diethyl sulfide in the B(OH)3-H2O2/H2O system
β Scribed by V. L. Lobachev; G. P. Zimtseva; Ya. V. Matvienko; E. S. Rudakov
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 114 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-5760
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π SIMILAR VOLUMES
The rate constants for the reactions OH(X 'II, kl k2 u=O) + NH3 --t HzO+ NH? and OII(X '11, u=O) + O3 -HO, + O2 were measured at 296K by the flash photolysis resonance fluorescence technique. The values of the rate constants thus obtained are kl = (4.1 +-0.6) X lo-l4 nndkz = (6.5 t 1.0) X lo-l4 in u
## Abstract The ability to use calculated OH frequencies to assign experimentally observed peaks in hydrogen bonded systems hinges on the accuracy of the calculation. Here we test the ability of several commonly employed model chemistriesβHF, MP2, and several density functionals paired with the 6β3
We report the observation of the O-+H,O+OH-+OH ion-molecule reaction following photodissociation of 0, within the 0: .H20 ion-dipole complex. Photoexcitation of the 0~ A % ,+X 'lIn dissociative transition in the 200-300 nm region initiates the reaction. The 0-'H20 reaction intermediate is the domina