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Kinetics of the hydroxymethylation of phenol II: values of rate parameters and results of simulation experiments

✍ Scribed by Mitsuo Higuchi; Shoichi Nohno; Mitsuhiro Morita; Shin-ichiro Tohmura

Book ID
104963104
Publisher
Springer
Year
1999
Tongue
English
Weight
643 KB
Volume
45
Category
Article
ISSN
1435-0211

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πŸ“œ SIMILAR VOLUMES

The reaction of phenol with formaldehyde
The reaction of phenol with formaldehyde: II. The ratio of ortho- and para-hydroxymethylphenol in the base-catalyzed hydroxymethylation of phenol.
✍ H. G. Peer πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 531 KB

## Abstract A kinetic study of the first step in the reaction of phenol and formaldehyde, the formation of __ortho‐__ and __para__‐hydroxymethylphenol, is described. It is found that when using NaOH or KOH as a catalyst under weakly alkaline conditions (pH = 8.5‐10.5) at 30Β° C, the __para__‐positi