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Kinetics of the hydrolysis of tetraethyl dithiopyrophosphate in aqueous dioxane solutions

โœ Scribed by V. E. Bel'skii; M. V. Efremova

Book ID
112434126
Publisher
Springer
Year
1968
Tongue
English
Weight
186 KB
Volume
17
Category
Article
ISSN
1573-9171

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The hydrolysis of phosphoranes in aqueou
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โœ A. Queen; A. E. Lemire; A. F. Janzen ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 247 KB

The entropy of activation for the hydrolysis of pentaphenoxyphosphorane in 25% aqueous dioxane is -188 J/mol deg. T h e enthalpy of activation is 22.5 kJ/mol, which is small for the relatively slow reaction. This suggests that the reaction is a multistep process having a preliminary equilibrium with