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Kinetics of the hydrolysis of arsenate(V) triesters

โœ Scribed by Baer, Carl D.; Edwards, John O.; Rieger, Philip H.


Book ID
120938328
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
372 KB
Volume
20
Category
Article
ISSN
0020-1669

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The copper complexes of 6 A -(2-aminoethylamino)-and 6 A -(3-aminopropylamino)-6 A -deoxy-b-cyclodextrin catalyse the hydrolysis of 4-tert-butyl-2-nitrophenyl dimethyl phosphate, with k inc =3.1ร—10 -2 and 2.3ร—10 -2 s -1 , and K d =4.3ร—10 -4 and 1.2ร—10 -3 M, respectively, in 0.05 M pH 7.0 HEPES buffe