Kinetics of the hydrogen transfer reaction of cyclohexene on palladium powder
✍ Scribed by S. Carrā; P. Beltrame; V. Ragaini
- Book ID
- 113172540
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- English
- Weight
- 628 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0021-9517
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In contrast to the usual two-liquid-phase process the hydrogenation of benzene is carried out in a continuously operated slurry (CST-) reactor containing only one liquid phase, an alkaline aqueous zinc chloride solution in which a ruthenium lanthanoxide catalyst is suspended. This new procedure give
## Abstract The rate of hydrogenation of cyclohexene, catalyzed by CoH~3~(PPh~3~)~3~, has been measured under various conditions and, based on these data, a mechanism has been postulated. For the individual steps of the mechanism enthalpy and entropy differences have been determined. The interpreta