Kinetics of the heterogeneous decomposition of iron pentacarbonyl
β Scribed by Herbert E. Carlton; Joseph H. Oxley
- Publisher
- American Institute of Chemical Engineers
- Year
- 1965
- Tongue
- English
- Weight
- 645 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0001-1541
No coin nor oath required. For personal study only.
β¦ Synopsis
versity of Texas. Thanks are due to the staff of that institution, as well as to Drs. H. E. Morris and W. H. Lane of Monsanto's Texas Division, for their help and comments. NOTATION Vol. I t , No. 1
π SIMILAR VOLUMES
The decomposition of alkaline hydrogen peroxide solutions at 20Β°C has been studied in the presence of both supported iron catalysts and in systems with iron initially in solution. Studies with an iron-alumina supported catalyst showed the decomposition reaction was first order with respect to total
The hydrogen peroxide decomposition kinetics were investigated for both "free" iron catalyst [Fe(II) and Fe(III)] and complexed iron catalyst [Fe(II) and Fe(III)] complexed with DTPA, EDTA, EGTA, and NTA as ligands (L). A kinetic model for free iron catalyst was derived assuming the formation of a r
## Abstract The heterocyclic compounds piperidine (Pip), piperazine (Pz), morpholine (Morph), and Nβmethyl piperazine (NβMPz) were used as ligands to form transition metal complexes with Ni(II), Cu(II), and Co(II) ions. These complexes were supported on Dowexβ50W resin so as to form new potential a