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Kinetics of the Grignard Reaction with Silanes in Diethyl Ether and Ether−Toluene Mixtures

✍ Scribed by Tuulmets, Ants; Nguyen, Binh T.; Panov, Dmitri; Sassian, Meeri; Järv, Jaak

Book ID
126097928
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
73 KB
Volume
68
Category
Article
ISSN
0022-3263

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Absolute rate coeficients for the reactions of the hydroxyl radical with dimethyl ether i k , ) and diethyl ether ( k 2 ) were measured over the temperature range 295-442 K. The rate coefficient data, in the units cm3 molecule s-l, were fitted to the Arrhenius equationsk,(T) = (1.04 2 0.10) x 10-"ex