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Kinetics of the Gas-Phase Recombination Reaction of Hydroxyl Radicals to Form Hydrogen Peroxide †

✍ Scribed by Sellevåg, Stig R.; Georgievskii, Yuri; Miller, James A.

Book ID
120082969
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
646 KB
Volume
113
Category
Article
ISSN
1089-5639

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✍ Kjell Fagerström; Anders Lund; Gharib Mahmoud; Jerzy T. Jodkowski; Emil Ratajcza 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 577 KB

The kinetics of the reactions CsH,+OH( t M) +products ( + M ) ( I ) were studied at room temperature by pulse radiolysis of C2H6/H20/SFb mixtures. The ethyl radical decay was followed by monitoring the UV absorption signals at 205 nm. The experimentally determined value of k, is (7.1 f 1.0) x lOto M