Kinetics of the Exchange of Hydrogen between Phosphine and Water: A Kinetic Estimate of the Acid and Base Strengths of Phosphine 1
β Scribed by Weston, Ralph E.; Bigeleisen, Jacob
- Book ID
- 127084603
- Publisher
- American Chemical Society
- Year
- 1954
- Tongue
- English
- Weight
- 564 KB
- Volume
- 76
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The oxidation of phosphinic, phenylphosphinic, and phosphorous acids by N-bromoacetamide (NBA) in acid solution, results in the formation of corresponding higher oxyacids of phosphorus. The reaction is first order with respect to NBA, second order in the oxyacid and inverse first in hydrogen ions. T
## Abstract The study shows that the alkaline hydrolysis of 2,2,2βtrichloroβ1βhydroxyethyl substituted phosphinates follows the same route as the corresponding phosphonates, Dipterex (**1**) and its ethyl analogue, giving O β P β C rearrangement products. The corresponding diphenyl and diethyl phos