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Kinetics of the Epoxidation of Castor Oil with Peracetic Acid Formed in Situ in the Presence of an Ion-Exchange Resin

✍ Scribed by Janković, Milovan R.; Sinadinović-Fišer, Snežana V.; Govedarica, Olga M.

Book ID
126445357
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
453 KB
Volume
53
Category
Article
ISSN
0888-5885

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In situ Formation of Peracetic Acid in I
In situ Formation of Peracetic Acid in Iron-Catalyzed Epoxidations by Hydrogen Peroxide in the Presence of Acetic Acid
✍ Megumi Fujita; Lawrence Que Jr. 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 102 KB 👁 2 views

## Abstract Iron complexes (tpa)Fe(OTf)~2~ (1) and (bpmen)Fe(OTf)~2~ (2) [tpa=tris‐(2‐pyridylmethyl)amine; bpmen=__N,N′__‐bis‐(2‐pyridylmethyl)‐__N,N′‐__dimethyl‐1,2‐ethylenediamine] were found to catalyze the __in situ__ formation of AcOOH from H~2~O~2~ and AcOH in the course of olefin oxidations.