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Kinetics of the decomposition of the XeF radical in polycrystalline XeF2and XeF4matrices

✍ Scribed by O. E. Yakimchenko; E. N. Degtyarev; V. N. Prusakov; Ya. S. Lebedev

Book ID
112362593
Publisher
Springer
Year
1980
Tongue
English
Weight
378 KB
Volume
16
Category
Article
ISSN
0040-5760

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Redox reactions in the XeF2/platinum flu
Redox reactions in the XeF2/platinum fluoride and XeF2/palladium fluoride systems and the conversion of XeF2 to XeF4 and Xe
✍ Neil Bartlett; Boris Ẑemva; Lionell Graham πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 781 KB

Liquid XeF2 at 140-150' oxidizes PtF4: 5XeF2 f 2PtF4 -2Xe2F3PtF6 + Xe f. The salt Xe2F3+PtF6-loses XeF2 at 70" in vacua: --Xe2F3PtF6-XeFPtF6 + XeF2 f. Pyrolysis of XeF+PtF6at 150-160" yields XeF4: XeFPtF6 -XePt2FlO + XeF4 f. The complex XePt2F10 loses XeF2 at 430": XePt2FlO +PtF4 + XeF2 +. XePt2Flo