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Kinetics of the Cyanoethylations of Ethanolamine, Acetylacetone and Methanol

✍ Scribed by Ogata, Yoshiro; Okano, Masaya; Furuya, Yoshiaki; Tabushi, Iwao


Book ID
127247235
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
351 KB
Volume
78
Category
Article
ISSN
0002-7863

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Kinetics and mechanism of the oxidation
✍ MiklΓ³s JΓ‘ky; JΓ‘nos Szammer; Edit Simon-Trompler πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 131 KB πŸ‘ 2 views

## Abstract The kinetics and mechanism of permanganate ion oxidation of acetylacetone (Acac) was studied in acidic and alkaline media. The rate constants for keto, enol, and enolate anions were determined and discussed. Delocalization of the π‐electrons of the double bond by conjugation results in