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Kinetics of the consecutive substitutions of ammonia by chloride ion in tetraamminepalladium(II) ion

✍ Scribed by Reinhardt, Richard A.; Sparkes, Robert K.


Book ID
126042891
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
529 KB
Volume
6
Category
Article
ISSN
0020-1669

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## Abstract The kinetics and mechanism of Hg^2+^‐catalyzed substitution of cyanide ion in an octahedral hexacyanoruthenate(II) complex by nitroso‐R‐salt have been studied spectrophotometrically at 525 nm (__Ξ»__~max~ of the purple‐red–colored complex). The reaction conditions were: temperature = 45.