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Kinetics of the catalytic oxidation of methanol to formaldehyde

✍ Scribed by Elio Santacesaria; Massimo Morbidelli; Sergio Carrà

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
787 KB
Volume
36
Category
Article
ISSN
0009-2509

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✦ Synopsis

Ahstraet

-The kinetics of the oxidation of methanol to formaldehyde, over iron molybdate as catalyst, have been studied. The kinetic runs have been performed with a CSTR reactor. The results can be described with a kinetic model derived on the basis of a redox mechanism partially hindered by the adsorption of water. The low temperatures used in the reactor (200-250°C) favour the formation of by-products, as dimetoxymethane. dimethyl ether and methylformate.

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