Kinetics of the autooxidation of iodine with regard to the bray-liebhafsky oscillatory reaction
✍ Scribed by Kaholek, Marian ;Treindl, Ludovít
- Book ID
- 105588806
- Publisher
- Springer
- Year
- 1998
- Tongue
- English
- Weight
- 267 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0133-1736
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The gas-phase reaction CH3SH + IZ has been studied spectrophotometrically over the temperature range of 476-604 K. It was found that the reaction undergoes H abstraction by I at 5575 K, leading to the formation of MeSI and followed by a secondary reaction which leads to the formation of MeSSMe: Tak
The gas phase reaction I, + HCOOCH, +HI + CH,I + CO, has been studied spectrophotometrically in a static system over the pressure ranges I, (6-39 torr) and HCOOMe (28-360 torr). In the temperature range 293-356', the initial rate of disappearance of I, is first order in [HCOOMe] and half-order in [I