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Kinetics of the anion-catalyzed Michael reaction of silyl ketene acetals. Initiation and propagation steps of group transfer polymerization

✍ Scribed by Brittain, William J.


Book ID
120384858
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
644 KB
Volume
110
Category
Article
ISSN
0002-7863

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## Abstract The rate of E/Z isomerization for the propagating end in group transfer polymerization (GTP) of methyl methacrylate (MMA) is comparable to the rate of propagation for bifluoride catalysis, in contrast to bibenzoate catalysis where propagation is faster. Methyl 2,2,4‐trimethyl‐5‐methoxy‐