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Kinetics of the acid hydrolysis of isoproturon in the absence and presence of sodium lauryl sulfate micelles

✍ Scribed by S. K. Gangwar; M. Z. A. Rafiquee

Publisher
Springer
Year
2006
Weight
192 KB
Volume
285
Category
Article
ISSN
0340-255X

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πŸ“œ SIMILAR VOLUMES

Kinetics of the alkaline hydrolysis of i
Kinetics of the alkaline hydrolysis of isoproturon in CTAB and NaLS micelles
✍ S. K. Gangwar; M. Z. A. Rafiquee πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 209 KB πŸ‘ 1 views

## Abstract Kinetics of the alkaline hydrolysis of isoproturon has been studied in the absence and presence of cetyltrimethylammonium bromide (CTAB) and sodium lauryl sulfate (NaLS) micelles. CTAB micelles were found to enhance the rate of reaction, while NaLS micelles inhibited the reaction rate.

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Pseudo-first-order rate constants (k obs ) for alkaline hydrolysis of 4-nitrophthalimide (NPTH) decreased by nearly 8-and 6-fold with the increase in the total concentration of cetyltrimethyl-ammonium bromide ([CTABr] T ) from 0 to 0.02 M at 0.01 and 0.05 M NaOH, respectively. These observations are