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Kinetics of the acetate catalyzed insertion of copper into a diacid porphyrin

✍ Scribed by N. Johnson; R. Khosropour; P. Hambright


Book ID
103107799
Publisher
Elsevier Science
Year
1972
Weight
149 KB
Volume
8
Category
Article
ISSN
0020-1650

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Stereochemistry of copper- and nickel-ca
✍ Jan-E. BΓ€ckvall; Ola Karlsson; Stig O. Ljunggren πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 French βš– 242 KB

Reaction of trans-1,2\_dideuterioethene oxide (1) with carbon dioxide, using copper and nickel catalysts, and subsequent analysis of the product ethene carbonate-d2 (2) by microwave spectroscopy, shows that the copper-catalyzed reaction is stereospecific (retention) whereas the nickel-catalyzed reac